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Atomic Structure and Wave Mechanics chemistry

Explain the Bohr Theory of hydrogen atom

admin April 3, 2025 No Comments

There was one major objection to the Rutherford model of atom and Bohr was the one to point it out. So while giving his Theory of hydrogen atom, he took…

Atomic Structure and Wave Mechanics chemistry

Explain the spectrum of Hydrogen

admin April 3, 2025 No Comments

According to Bohr, when an electron from its initial stationary orbit with n= ni jumps to another (lower) stationary orbit with n=nf, it emits energy equal to the difference between…

Atomic Structure and Wave Mechanics chemistry

Explain in detail how Sommerfeld extended the Bohr Theory

admin April 3, 2025 No Comments

Bohr was able to calculate the radii as well energies of the stationary orbit around the nucleus in an atom and those calculated values were found to be in a…

Atomic Structure and Wave Mechanics chemistry

What were the objections to the Bohr model of atom?

admin April 3, 2025 No Comments

Though the Bohr and sommerfeld were able to explain the atomic spectra of hydrogen and like species but still there were many anomalies to their theory. Both Bohr’s theory and…

Atomic Structure and Wave Mechanics chemistry

Explain the dual nature of electron?

admin April 3, 2025 No Comments

In 1905, it was Einstein who suggested the concept of light having a dual nature; particle and wave nature. In a similar way, Louise de Broglie suggested that electron also…

Atomic Structure and Wave Mechanics chemistry

What is the difference between matter and electromagnetic waves?

admin April 3, 2025 No Comments

Electromagnetic waves are very much different from the matter waves and in many ways. a) Speed of matter waves is very much less than the speed of electromagnetic waves. b)…

Atomic Structure and Wave Mechanics chemistry

Derive the Bohr angular momentum from de Broglie’s relation

admin April 3, 2025 No Comments

Let us consider an electron revolving around a nucleus of an atom. The wave train formed by it is as shown in figure. Now, for the wave to be in…

chemistry Thermodynamics Third Law of Thermodynamics

Define third law of thermodynamics. Discuss the importance of third law of thermodynamics.

admin April 2, 2025 No Comments

The third law of thermodynamics states that: “The entropy of all the perfect crystalline solids is zeros at absolute zero temperature”. The third law of thermodynamics is also referred to…

chemistry Thermodynamics Third Law of Thermodynamics

What is irreversible process? Give an example of irreversible process.

admin April 2, 2025 No Comments

Irreversible process: An Irreversible process is one in which heat is transferred through a finite temperature. Irreversible process is also known as spontaneous process because these processes take place at…

chemistry Thermodynamics Third Law of Thermodynamics

Define the Nernst Heat Theorem

admin April 2, 2025 No Comments

The Nernst Heat Theorem Let us consider the Gibbs-Helmholtz equation which includes chemical reaction i.e.: ∆G – ∆H = T (∂ (∆G)/∂T) P ………………………………….. (1) Where ∆G ——-> change in…

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