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Chemical Kinetics chemistry

What will be the effect of addition of inert gas on the equilibrium constant?

admin April 4, 2025 No Comments

Effect of addition of inert gas like helium, neon etc has the following effects on the equilibrium constant: There are two cases on which equilibrium depends. These are: (1) Addition…

chemistry Free Energy and Chemical Equilibria

What are the units of Equilibrium constant?

admin April 4, 2025 No Comments

The Equilibrium constant expression involves the concentrations or partial pressures of the reactants and products. The units of Equilibrium constant K will depend on the number of moles of reactants…

chemistry Free Energy and Chemical Equilibria

At 700 K, the equilibrium constant Kp, for the reaction 2 SO3 (g) ⇌ 2 SO2 (g) + O2 Is 1.8 X 10-3 kPa. What is the numerical value in moles per liter of Kc for the reaction at the same temperature?

admin April 4, 2025 No Comments

Relation between Kp and Kc is given as: Kp = Kc (RT) ∆n Kc = Kp / (RT) ∆n T = 700 K R = 8.314 J mol -1 K-1…

chemistry Free Energy and Chemical Equilibria

The degree of dissociation of PCl5 at a certain temperature and under atmospheric pressure is 0.2. Calculate the pressure at which it will be half dissociated at the same temperature.

admin April 4, 2025 No Comments

PCl5 dissociates as: PCl5 ⇌ PCl3 Cl2 If α is the degree of dissociation at certain temperature under atmospheric pressure, then Initial concentration: PCl5 = 1 PCl3 = 0 Cl2…

chemistry Free Energy and Chemical Equilibria

Derive an expression for the degree of dissociation, α, in terms of Kp

admin April 4, 2025 No Comments

For the homogeneous gaseous reaction 2 AB2 (g) ⇌ 2 AB (g) + B2 (g) Derive an expression for the degree of dissociation, α, in terms of Kp and total…

Chemical Kinetics chemistry

What is the difference between rate of reaction and reaction rate constant?

admin April 4, 2025 No Comments

Difference between rate of reaction and reaction rate constant are as follows: RATE OF REACTION REACTION RATE CONSTANT Rate of reaction is the change in concentration of a reactant or…

Chemical Kinetics chemistry

Discuss the molecularity of complex reactions.

admin April 4, 2025 No Comments

In case of chemical reactions i.e. reactions involving a number of atoms, ions, molecules of the reactants in the balanced equation, the chances for all the atoms, ions or molecules…

Chemical Kinetics chemistry

Explain the Mechanism of a Reaction?

admin April 4, 2025 No Comments

A series of step reactions or elementary processes proposed to account for the overall reaction is called the mechanism of the reaction. The writing of step reactions is usually based…

Chemical Kinetics chemistry

Distinguish between order of a reaction and molecularity of a reaction?

admin April 4, 2025 No Comments

The main difference between the order of a reaction and molecularity of a reaction are given below: ORDER OF A REACTION MOLECULARITY OF A REACTION It is sum of the…

Chemical Kinetics chemistry

What is the difference between photochemical reactions and thermochemical reactions?

admin April 4, 2025 No Comments

Difference between photochemical reactions and thermochemical reactions are discussed below: THERMOCHEMICAL REACTIONS PHOTOCHEMICAL REACTIONS These reactions involve absorption or evolution of heat. These reactions involve absorption of light. They can…

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