Calculate the pH of a buffer solution containing 0.2 mole of NH4Cl and 0.1 mole of NH4OH per litre. Kb for NH4OH = 1.85 x 10-5.
According to Henderson – Hasselbalch equation: pOH = pKb + log (/ ) pKb = – log Kb = – log .85 x 10-5 = 4.733 Therefore, pOH = 4.733…