Calculate the pH of the 0.561 g of KOH dissolved in 200 mL of solution.

0.561 g of KOH dissolved in 200 mL of solution will have:
Moles of KOH = 0.561 / 56 = 1.0 x 10-2
As molar mass of KOH = 56 u
Concentration of solution = (moles of KOH / vol. of solution) x 1000
= (1.0 x 10-2 / 200) x 1000
= 5.0 x 10-2 M
As KOH is completely ionized therefore,
[OH] = [KOH] = 5.0 x 10-2 M
[H3O+] = Kw / [OH]
= 1 x 10-14 / 5.0 x 10-2
= 2.0 x 10-13
pH = – log [H3O+] = – log (2.0 x 10-13)
= – log 2.0 + 13 = 0.301 + 3 = 12.699

Hence, the pH of the 0.561 g of KOH dissolved in 200 mL of solution is equal to 12.699

Category: Ionic Equilibria

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